It seems like your nemesis has some flaws to be exploited. Is he OCD? What is the work environment like? A cube farm? Private office? Something else?
Start by spreading the love. Crack open a can of tuna ever so slightly. Hide it deep within his desk or cube farm environs.
^ I like the tuna idea but go a little further,
An anchovy or two and a little sugar, wrap in a tissue and deposit in a drawer.
It'll start to ferment quite quickly and the smell is pretty nasty.
A friend once told me about the "milk bomb" prank where you fill an airtight glass jar with sour milk, insert a chicken or turkey leg into the liquid, then screw the lid on. Hide the jar in the victim's car on a hot summer day and the thing eventually explodes, practically ruining their car with the stench. Ah, here's a how-to online, of course.
http://www.urbandictionary.com/define.php?term=milk+chicken+bomb